ORIGINAL_ARTICLE
Copper Coordinated Congo-Red as a Solvent Assisted Selective Fluorometric and Colorimetric Chemosensor for Determination and Naked-Eye Detection of Multiple Analytes in Nanomolar Scale: A Reversible Fluorescent CN−/CO32− Switch that Works as Keypad Lock
A new diazo based, Congo-Red-Cu , was developed to act as an ‘Off–On’ reversible fluorescent probe for CN− detection. The changes in solvent composition has been shown greatly effective on selectivity of anion sensing through eliminate of sulfite interference. Increasing the amount of ethanol up to 5% (v/v) cause a dramatic development in selectivity of CN−via inhibitory effect on sulfite interferent. The chemosensing behavior of the CR-Cu has been demonstrated through fluorescence, absorption, visual color changes and FT-IR studies. This chemosensor (CR-Cu) has been shown a significant visible color change and displays a remarkable fluorescent switch on in the presence of CN− ions. The ‘in situ’ prepared CN− complexes of CR-Cu shows high “Turn-Off” selectivity toward CO32− over the other anions. The detection limits for CN− were 90 and 20 nM for colorimetric and fluorometric methods respectively, that is far lower than the WHO guideline of 1.9 µM. The complex of CN− with CR-Cu also displayed ability to detect up to 15 nM CO32− among other competing anions through a fast response time of less than 30 s which is much lower than most recently reported chemosensor probes. It has been possible to build an INHIBIT logic gate for two binary inputs viz., CN− and CO32− by monitoring the fluorescence emission band at 446 nm as output. The development of fluorometric an ‘‘Off–On’’ reversible switch for three chemical inputs Cu2+, CN− and CO32− ions and mimics a molecular level keypad lock.
https://ijac.journals.pnu.ac.ir/article_3119_21ef8451ba6b36abcf445e698a0b13c0.pdf
2016-09-01
76
87
Colorimetric Chemosensor
Fluorescent Modulation
Solvent Assisted
Cyanide Recognition
Carbonate Recognition
Keypad Lock
Hossein
Tavallali
tavallali@pnu.ac.ir, tavallali@yahoo.com
1
Department of Chemistry, Payame Noor University, P.O. BOX, 19395-3697, Tehran, Iran
LEAD_AUTHOR
Gohar
Deilamy-Rad
deilamy_rad@yahoo.com
2
Department of Chemistry, Payame Noor University, P.O. BOX, 19395-3697, Tehran, Iran
AUTHOR
Abolfath
Parhami
rezaparhami@yahoo.com
3
Department of Chemistry, Payame Noor University, P.O. BOX, 19395-3697, Tehran, Iran
AUTHOR
Sajedeh
Lohrasbi
lohrasbi_561@yahoo.com
4
Department of Chemistry, Payame Noor University, P.O. BOX, 19395-3697, Tehran, Iran
AUTHOR
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[26] H. Tavallali, G. Deilamy-Rad, A. Parhami and E. Abbasiyan, A novel and efficient colorimetric chemosensor for detection and determination of biologically important ions in DMSO/H2O media using bromo pyrogallol red chemosensors with analytical applications, J. Photochem. Photobiol. B 115 (2012) 51–57.
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[27] H. Tavallali, G. Deilamy-Rad, A. Parhami and S.Z. Mousavi, A novel development of dithizone as a dual-analyte colorimetric chemosensor: detection and determination of
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cyanide and cobalt (II) ions in dimethyl sulfoxide/water media with biological applications, J. Photochem. Photobiol. B 125 (2013) 121–130.
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[29] H. Tavallali, G. Deilamy-Rad, A. Parhami and N. Hasanli, A novel cyanide-selective colorimetric and fluorescent chemosensor: First molecular security keypad lock based on phosphotungstic acid and CN− inputs, J. Hazard. Mater. 266 (2014) 189–197.
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[30] H. Tavallali, M.R. Baezzat, G. Deilamy-Rad, A. Parhami and N. Hasanli, An ultrasensitive and highly selective fluorescent and colorimetric chemosensor for citrate ions based on rhodamineB and its application as the first molecular security keypad lock based on phosphomolybdic acid and citrate inputs, J. Luminescence 160 (2015) 328–336.
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50
ORIGINAL_ARTICLE
N-[4-(Dimethyl Amino) Benzylidene] Benzoxide as a New Luminophor in Peroxyoxalate Chemiluminescence System for the Determination of Sucrose
In this work, the first, intense and efficient POCL arising from the reaction of bis (2, 4, 6-trichlrophenyl) oxalate (TCPO) with hydrogen peroxide in the presence of N-[4-(dimethyl amino) benzylidene] benzoxide (Nitrone) as a new luminophor has been reported. The relationships between the chemiluminescence intensity and concentrations of all reagents were investigated. The quenching effect of some cations and compounds such as Fe3+, Co2+, Cu2+, Mn2+, Ni2+, Cd2+ ions and imidazole, L-Histidine, L-Tyrosine, D-(+)-Lactose, and D-(+)-Sucrose, on the POCL system were investigated. The KQ values were calculated from Stern–Volmer equation. It was found that the KQ values decreases in the order: Co2+ > Fe3+ > Cu2+ > Mn2+ > Ni2+ > Cd2+ and D-(+)-Lactose > Imidazole > L-Tyrosine > L-Histidine > D-(+)-Sucrose. Dynamic range and detection limit of all quencher were determined. Sucrose has the best dynamic range and low detection limit, so sucrose considered as an analyte and then the total sucrose extracted from sugar beet as real sample was measured by this proposed method. Dynamic range, detection limit, mean intra-day and inter-day relative standard deviation (RSD%) were 6.67×10-7- 1.20×10-5, 1.0×10-8, 5.62%, 7.25% (n=3) respectively. For accuracy determination, the percentage recovery was found 97.4%- 104.3%. All interferences were investigated and Co2+, D-(+)-Lactose had most interference. Sucrose percentage of the measured sample was 17 percent. These results are comparable with the results of the standard method to determine the sucrose and is acceptable.
https://ijac.journals.pnu.ac.ir/article_2752_7d56cd0e72f7648f1bdd00f012b63c4f.pdf
2016-09-01
88
95
Efficient Peroxyoxalate Chemiluminescence
Nitrone
Quenching
Effect Sucrose
Ali
Yeganeh-Faal
yeganehfaal@yahoo.com
1
Department of Chemistry, Payame Noor University (PNU), P.O. BOX, 19395-3697, Tehran, Iran
LEAD_AUTHOR
Ghazal
Parvan
yeganehfaal@pnu.ac.ir
2
Department of Chemistry, Payame Noor University (PNU), P.O. BOX, 19395-3697, Tehran, Iran
AUTHOR
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46
ORIGINAL_ARTICLE
Optimization of Lead-Selective Membrane Electrode Using Central Composite Experimental Design, and Study of Its Behavior with Electrochemical Impedance Spectroscopy
In this work, response surface methodology in conjunction with central composite design for modeling and optimization of the influence of some process variables (polyvinyl chloride (F1), ionophore (F2), additive (F3) and plasticizer (F4) amounts), on the performance of polyvinyl chloride membrane lead (ІІ) ion-selective electrode is discussed. The slope of 29.1 ± 0.1 mV at the optimal amounts of polyvinyl chloride (0.0283 g), ionophore (0.0074 g), additive (0.002 g) and plasticizer (0.060 g) has been achieved. The electrode exhibited a linear potential response to lead (II) in the concentration range of 1.0 × 10-5 mol L-1 to 1.0 × 10-1 mol L-1 over pH range of 3.0 - 5.5. Greatly, the alternating current impedance technique was applied to investigate the response mechanism of the electrode. The results were obtained from electrochemical impedance spectroscopy shows a linear concentrations range of 1.0 × 10-6 mol L-1 to 1.0×10-1 mol L-1 and in comparison with potentiometry, the pH range increased to 2.5 − 6.0.
https://ijac.journals.pnu.ac.ir/article_3114_81a39ac7d5eb46e068242d42779fcadb.pdf
2016-10-16
96
104
Ion-Selective Electrode
Polyvinyl Chloride Membrane
Ionophore
Response Surface Methodology
Central Composite Design
Mohammad
Mazloum-Ardakani
mazloum@yazd.ac.ir
1
Department of Chemistry, Faculty of Science, Yazd University, Yazd, Iran
LEAD_AUTHOR
Azimeh
Mandegari
2
Departmentof Chemistry, Payame Noor University, P.O. Box 19395-4697 Tehran, Iran
AUTHOR
Alireza Khoshroo
Khoshroo
3
Department of Chemistry, Faculty of Science, Yazd University, Yazd, Iran
AUTHOR
Saeed
Masoum
4
Department of Analytical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran
AUTHOR
Hadi
Kargar
5
Departmentof Chemistry, Payame Noor University, P.O. Box 19395-4697 Tehran, Iran
AUTHOR
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8
[8] M. Mazloum Ardakani, M. Salavati-Niasari and M. Jamshidpoor, Selective nitrate poly (vinylchloride) membrane electrode based on bis (2-hydroxyacetophenone) ethylenediimine vanadyl (IV), Sens. Actuators B Chem. 101 (2004) 302–307.
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[12] H. Abdolmohammad-Zadeh, A. Naseri, M. Galeh-Assadi and S. Shabkhizan, Optimization of solid-phase extraction based on a new sol-gel material using a response surface methodology for the determination of copper in water samples by flame atomic absorption spectrometry, Int. J. Environ. Anal. Chem. 93 (2013) 279–297.
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[13] M. Mazloum-Ardakani, A.D. Manshadi, M. Bagherzadeh and H. Kargar, Impedimetric and Potentiometric Investigation of a Sulfate Anion-Selective Electrode: Experiment and Simulation, Anal. Chem. 84 (2012) 2614– 2621.
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[16] M. Mazloum-Ardakani, L. Hosseinzadeh and A. Khoshroo, Label-free electrochemical immunosensor for detection of tumor necrosis factor α based on fullerenefunctionalized carbon nanotubes/ionic liquid, J. Electroanal. Chem. 757 (2015) 58–64.
17
[17] M. Mazloum-Ardakani, L. Hosseinzadeh and A. Khoshroo, Ultrasensitive Electrochemical Immunosensor for Detection of Tumor Necrosis Factor-α Based on Functionalized MWCNT-Gold Nanoparticle/Ionic Liquid Nanocomposite, Electroanalysis. 27 (2015) 2518–2526.
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[20] M. Mazloum-Ardakani and A. Khoshroo, Enhanced performance of dye-sensitized solar cells with dual-function coadsorbent: reducing the surface concentration of dye-iodine complexes concomitant with attenuated charge recombination, Phys. Chem. Chem. Phys. 17 (2015) 22985–22990.
21
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[25] M. Mazloum-Ardakani, A. Khoshroo and L. Hosseinzadeh, Simultaneous determination of hydrazine and hydroxylamine based on fullerene-functionalized carbon nanotubes/ionic liquid nanocomposite, Sens. Actuators B Chem. 214 (2015) 132–137.
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28
ORIGINAL_ARTICLE
Study of the Adsorption of L-Phenylalanine, L-Tryptophan, and L-Tyrosine from Aqueous Samples by Fe3O4 Modified Magnetic Nanoparticles with Ionic Liquid
Fe3O4 nanoparticles and their binary mixtures ([C8MIM]-Fe3O4) with 1-Octyl-3-methylimidazolium bromide were prepared and characterized as ionic liquid for using in the adsorption of phenylalanine, tryptophan, and tyrosine. The characteristics of [C8MIM]-Fe3O4 nanoparticles were investigated via using TEM, XRD and FTIR techniques. The pH of the point of zero charge (pHpzc) of both Fe3O4 and [C8MIM]-Fe3O4 were obtained based on the experimental curves corresponding to the immersion technique. Experimental results were obtained under optimum operational conditions of: nanoparticle amount of 0.015 g and a contact times of 5, 10, 15 minutes for tryptophan (Trp), tyrosine (Tyr) and phenylalanine (Phe), respectively, when initial concentration of each amino acid was 5.0×10−4 mol L−1. The isotherm evaluations revealed that the Freundlich model attained better fits to the equilibrium data than the Dubinin-Radushkevich model. The maximum obtained adsorption capacities of Tyr, Trp and Phe were 12.74, 3.55 and 35.62 mg amino acid per gram of adsorbent, respectively. The applicability of pseudo-first order and pseudo-second order kinetic models was estimated on the basis of comparative analysis of the corresponding rate parameters, equilibrium adsorption capacity and correlation coefficients. Furthermore, the adsorption processes were found endothermic. Both phenylalanine and tyrosine were desorbed from [C8MIM]-Fe3O4 nanoparticles by using NaOH aqueous solution with concentrations of 1.0 and 2.0 mol L−1, respectively. Tryptophan was completely desorbed in the presence of a mixture of 1.0 mol L−1 NaCl and 1.0 mol L−1 NaOH. The nanoparticles thus were recycled.
https://ijac.journals.pnu.ac.ir/article_3115_ba16c64768868ca76cdfb4947abfd5ed.pdf
2016-09-01
105
115
Magnetic Nanoparticle
ionic liquid
adsorption
Amino acids
Sedigheh
Kamran
kamran_ss5@yahoo.com; s.kamran@pnu.ac.ir
1
Departmentof Chemistry, Payame Noor University, P.O. Box 19395-4697 Tehran, Iran
LEAD_AUTHOR
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45
ORIGINAL_ARTICLE
Quantitative Study of 13C Chemical Shifts of β-Naphthalenes Using 2D Image Approach and Density Functional Theory Computation
A 2D image approach has been used to predict 13C NMR chemical shifts of β-naphthalene derivatives. In multivariate image analysis-Quantitative structure property relationship (MIA-QSPR) study, descriptors correlating with dependent variable are pixels (binaries) of 2D chemical structures; Variant pixels in the structures (substitutes) account to explained variance in the property (chemical shifts). A case study is carried out in order to predict 13C NMR chemical shifts of 10 carbon positions of 24 mono substituted β-naphthalenes. The resulted descriptors were subjected to principal component analysis (PCA) and the most significant principal components (PCs) were extracted. Then, MIA-QSPR modeling was done by means of principal component regression (PCR) and principal component –artificial neural network (PC-ANN) methods. A correlation ranking procedure is proposed here to select the most relevant set of PCs as inputs for PCR and PC-ANN modeling methods. Here, the 13C chemical shifts of studied compounds were predicted using density functional theory (DFT) calculations, too. The widely applied method of gauge included atomic orbital (GIAO) B3LYP/6-311++ G have been used. The performance of the GIAO was also compared with PCR and PC-ANN models. Results showed the superiority of the PC-ANN over GIAO and PCR models. Finally, 13C NMR chemical shifts of studied compounds were calculated using ChemDraw program.
https://ijac.journals.pnu.ac.ir/article_3021_0cafc2ddf1c805b5a939e9b6fc7b1a45.pdf
2016-09-10
116
126
Multivariate Image Analysis
density functional theory
13C Chemical Shift
β-Naphthalenes
Zahra
Garkani-Nejad
z_garkani@uk.ac.ir
1
Department of Chemistry, Faculty of Science, Shahid Bahonar University of Kerman, Kerman, Iran
LEAD_AUTHOR
Marziyeh
Poshteh-Shirani
2
Department of Chemistry, Isfahan University of Technology, Isfahan, Iran
AUTHOR
[1] S.Witkowski, D. Maciejewska and I. Wawer, 13C NMR studies of conformational dynamics in 2,2,5,7,8-pentamethylchroman-6-ol derivatives in solution and the solid state, J. Chem. Soc. Perkin Trans. 2 (2000) 1471– 1476.
1
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7
[8] R. Kiralj and M.M.C. Ferreira, Simple Quantitative Structure−Property Relationship (QSPR) Modeling of 17O Carbonyl Chemical Shifts in Substituted Benzaldehydes Compared to DFT and Empirical Approaches, J. Phys. Chem. A 112 (2008) 6134–6149.
8
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9
[10] M. Goodarzi, T. Chen and M.P. Freitas, QSPR predictions of heat of fusion of organic compounds using Bayesian regularized artificial neural networks, Chemom. Intell. Lab. Sys. 104 (2010) 260-264.
10
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13
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14
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17
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ORIGINAL_ARTICLE
Removal of Manganese Ions From Aqueous Solutions Using Polymers Derivations of Poly (Styrene-Alt- Maleic Anhydride)
In this study chelating resins have been considered to be suitable materials for the recovery of Manganese(II) ions in water treatments. These modified resins were further reacted with 1,2-diaminoethan in the presence of ultrasonic irradiation for the preparation of a tridimensional chelating resin on the Nano scale for the recovery of Manganese II) ions from aqueous solutions. In this work we used copolymers derivate resin of poly (styrene – Alternative - Maleic Anhydride) and Atomic Absorption Spectroscopy for removing and determining Manganese(II) ions .The method is simple, sensitive, inexpensive and fast. The adsorption behavior of Manganese(II) ions were investigated by the synthesis of chelating resins at various pH’s. The prepared resins showed a good tendency for removing the selected metal ions from aqueous solution, even at acidic pH. Also, the prepared resins were examined for the removal of Manganese(II) ions from real samples such as industrial wastewater and were shown to be very efficient at adsorption in the cases of Manganese(II) ions . The pseudo-first-order, pseudo-second-order and intra-particle diffusion kinetics equations were used for modeling of adsorption data and it was shown that pseudo-second-order kinetic equation could best describe the adsorption kinetics. The intra-particle diffusion study revealed that external diffusion might be involved in this case. The resins were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray diffraction analysis.
https://ijac.journals.pnu.ac.ir/article_2737_35d11e3b784465cab22998f1812cdda0.pdf
2016-09-01
127
136
Removal of Manganese
X-Ray Diffraction
Chelating Resins
scanning electron microscopy
Naser
Samadi
1
Department of Analytical Chemistry, Faculty of Chemistry, Urmia University, Urmia, Iran
LEAD_AUTHOR
Reza
Ansari
2
Department of Chemistry, Faculty of Science, University of Guilan, University Campus 2,
AUTHOR
Bakhtiar
Khodavirdilo
b.khodavirdilo@yahoo.com
3
Department of Chemistry, Faculty of Science, University of Guilan, University Campus 2,
AUTHOR
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[4] M.J. Gonza´lez-Mun˜ oz, M.A. Rodrı´guez, S. Luque and J.R.A ´lvarez, Recovery of heavy metals from metal industry wastewaters by chemical precipitation and nanofiltration, Desalination 200 (2006) 742– 744.
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[5] R. Kiefer, A.I. Kalinitchev and W.H. Ho¨ ll, Column performance of ion exchange resins with aminophosphonate functional groups for elimination of heavy metals, React. Funct. Polym. 67 (2007) 1421–1432.
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[32] J.C.P. Vaghetti, E.C. Lima, B. Royer, B.M. da Cunha, N.F.Cardoso, J.L. Brasil and S.L.P. Dias, Pecan nutshell as biosorbent to remove Cu(II), Mn(II) and Pb(II) from aqueous solutions, J. Hazard. Mater. 162 (2009) 270–280.
32
ORIGINAL_ARTICLE
Removal of Lead and Zinc Ions from Aqueous Solutions Using Naphthalene Modified with Malononitrile Derivative
Removal of Pb(II) and Zn(II) ions from aqueous solutions using naphthalene modified with 2-(3,4,5-trimethoxybenzylidene) malononitrile(TMBM) as synthetic adsorbent was investigated. It was characterized by FT-IR. Batch method was applied for testing of adsorption behavior. Adsorption experiments showed, the new sorbent has high selectivity and good adsorption for removal of lead and zinc ions from aqueous solutions. Equilibration time was 5 min for zinc and 15 min for lead. There was little effect of salt on removal of the ions. The maximum adsorption capacities for Pb(II) and Zn(II) were 88.5 and 38.9 mg g-1, respectively. The thermodynamic studies indicated that the adsorption was spontaneous, exothermic and endothermic process for lead and zinc, respectively.
https://ijac.journals.pnu.ac.ir/article_2751_d5bc1f16df664b850acd2f511c4b7acc.pdf
2016-06-01
137
144
adsorption
lead
malononitrile
Naphthalene
zinc
Fatemeh
Sabermahani
fatemehsaber2003@yahoo.com
1
Department of Chemistry, PayameNoor University (PNU), P.O. BOX 19395-3697, Tehran, IRAN
LEAD_AUTHOR
Fatemeh
Ziaaddini
f_ziaaddini@yahoo.com
2
Department of Chemistry, PayameNoor University (PNU), P.O. BOX 19395-3697, Tehran, IRAN
AUTHOR
Zahra
Hassani
hassanizahra@yahoo.com
3
Department of New Materials, Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, Kerman, Iran
AUTHOR
[1] H. Ucun, Y.K. Bayhan, Y. Kaya, A. Cakici and O.F. Algur, Biosorption of lead(II) from aqueous solution by cone biomass of Pinus sylvestris, Desalination 154 (2003) 233-238.
1
[2] V.A. Lemos, W.N.L. Santos, J.S. Santos and M.B. Carvalho, On-line preconcentration system using a mini column of polyurethane foam loaded with Me-BTABr for zinc determination by Flame Atomic Absorption Spectrometry, Anal. Chim. Acta 481 (2003) 283-290.
2
[3] E.J. Kim, S. Park, H. Hong, Y. Choi and J. Yang, Biosorption of chromium (Cr(III)/Cr(VI)) on the residual microalga Nannochloris oculata after lipid extraction for biodiesel production, Bioresource Technol. 102 (2011)1155-1160.
3
[4] C.M. Monteiro, P.M.L. Castro and F.X. Malcata, Biosorption of zinc ions from aqueous solution by the microalga Scenedesmus obliquus, Environ. Chem. Lett. 9 (2011) 169-176.
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[5] A. Mudhoo, V.K. Garg and S. Wang, Removal of heavy metals by biosorption, Environ. Chem. Lett. 10 (2012) 109-117.
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[6] H. Kinoshita, Y. Sohma, F. Ohtake, M. Ishida, Y. Kawai, H. Kitazawa, T. Saito and K. Kimura, Biosorption of heavy metals by lactic acid bacteria and identification of mercury binding protein, Res. Microbiol. 164 (2013) 701-709.
6
[7] O.S. Amuda, A.A. Giwa and I.A. Bello, Removal of heavy metal from industrial wastewater using modified activated coconut shell carbon, Biochem. Eng. J. 36 (2007)174181.
7
[8] M.J. Ayotamuno, R.N. Okparanma, S.O.T. Ogaji and S.D. Probert, Chromium removal from flocculation effluent of liquid-phase oilbased drill-cuttings using powdered activated carbon, Appl. Energ. 84 (2007) 1002-1011.
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[9] A.K. Bhattacharya, T.K. Naiya, S.N. Mandal and S.K. Das, Chem. Eng. J. 137 (2008) 529541.
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[10] M. Koroki, S. Saito, H. Hashimoto, T. Yamada and M. Aoyama, Removal of Cr(VI) from aqueous solutions by the culm of bamboo grass treated with concentrated sulfuric acid, Environ. Chem. Lett. 8 (2010) 59-61.
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[11] C.M. Monteiro, P.M.L. Castro and F.X. Malcata, Capacity of simultaneous removal of zinc and cadmium from contaminated media, by two microalgae isolated from a polluted site, Environ. Chem. Lett. 9 (2011) 511-517.
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[12] J. Volmajer, R. Toplak, S. Bittner and A.M. Le Marechal, 2-Oxiranecarbonitriles in the synthesis of linked quinono heterocyclic derivatives, ARKIVOC 14 (2003) 49-61.
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[13] E.I. El-Shafey, Removal of Zn(II) and Hg(II) from aqueous solution on a carbonaceous sorbent chemically prepared from rice husk, J. Hazard. Mater. 175 (2010) 319-327.
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[14] H.N. Bhatti, B. Mumtaz, M.A. Hanif and R. Nadeem, Removal of Zn(II) ions from aqueous solution using Moringa oleifera Lam. (horseradish tree) biomass, Process Biochem. 42 (2007) 547-553.
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[17] K.L. Wasewar, M. Atif, B. Prasad and I.M. Mishra, Batch adsorption of zinc on tea factory waste, Desalination 244 (2009) 6671.
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[18] R.P. Suresh Jeyakumar and V. Chandrasekaran, Adsorption of lead(II) ions by activated carbons prepared from marine green algae: Equilibrium and kinetics studies, Int. J. Ind. Chem. 5 (2014) 2-10.
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[19] N. Gupta, S.S. Amritphale and N. Chandra, Removal of Zn (II) from aqueous solution by using hybrid precursor of silicon and carbon, Bioresource Technol. 101 (2010) 3355-3362.
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[20] R. Han, J. Zhang, W. Zou, J. Shi and H. Liu, Equilibrium biosorption isotherm for lead ion on chaff, J. Hazard. Mater. 125 (2005) 266271.
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[21] P. Chand and Y.B. Pakade, Removal of Pb from water by adsorption on apple pomace: Equilibrium, kinetics, and thermodynamics studies, J. Chem. doi: 10.1155/2013/164575.
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[22] L. Yuan and Y. Liu, Removal of Pb(II) and Zn(II) from aqueous solution by ceramisite prepared by sintering bentonite, iron powder and activated carbon, Chem. Eng. J. 215-216 (2013) 432-439.
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29
ORIGINAL_ARTICLE
Design of an Optical Sensor for Aluminium(III) Determination Based on Immobilization of Eriochrome Cyanine R on a Triacetylcellulose
A selective optical sensor based on immobilization of Eriochrome Cyanine R for the determination of Al(III) ions in aqueous solution has been developed. The method is based on the spectrophotometric measurement of complex Eriochrome Cyanine R-aluminium at 537 nm. The sensing membrane is made of a triacetylcellulose film containing Eriochrome Cyanine R colorimetric reagent immobilized as an ion pair with methyltrioctylammonium chloride. The response of the sensor is based on the Eriochrome Cyanine R absorbance decrease by the coordination of Al(III) ions. At pH= 6.0, the linear dynamic rangeis varied from 3.22×10-8 to 4.10×10-5 mol L-1 with a detection limit of 1.2× 10-8 mol L-1. A dynamic working range, detection limit, sensitivity, selectivity and the response time were discussed in detail. The response was pH dependent. The membrane responds to Al(III) ions irreversibly by changing color from pink to blue. The membrane was regenerated in less than 30 seconds with 0.1 mol L-1 EDTA solution and was ready for further measurements. The response time of the sensor was within 16 min depending on the concentration of Al (III) ions. The sensor response was found to have a repeatability and reproducibility of 1.62% and 3%, respectively. The sensor provides appropriate selectivity to Al(III) ions over transition metal cations, including Co(II), Ni(II), Fe(III), Cu(II) and Zn(II). The sensor has been used for the determination of Al(III) ions in potable water and aluminium – magnesium syrup.
https://ijac.journals.pnu.ac.ir/article_2738_9d4a5042ad2c3c6c90645bfa4590afa4.pdf
2016-06-11
145
152
Optical sensor
Triacetylcellulose Membrane
Eriochrome Cyanine R
Aluminium
Lipophilic Ion Pairs
Habibollah
Khajehsharifi
khajeh_h@yahoo.com
1
Department of Chemistry, College of Sciences, Yasouj University, P. O. Box 7591-874934, Yasouj, Iran
LEAD_AUTHOR
Aida
Solhjoo
aida_86as@yahoo.com
2
Department of Chemistry, College of Sciences, Yasouj University, P. O. Box 7591-874934, Yasouj, Iran
AUTHOR
Mohammad Mahdi
Bordbar
mohammadmahdibordbar@gmail.com
3
Department of Chemistry, College of Sciences, Yasouj University, P. O. Box 7591-874934, Yasouj, Iran
AUTHOR
[1] I.M. Steinberg, A. Lobnik and O.S. Wolfbeis, Characterisation of an optical sensor membrane based on the metal ion indicator Pyrocatechol Violet, Sens. Actuators B 90 (2003) 230–235.
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