Shahryar Pashaei; Soleyman Hosseinzadeh; Nahid Mohammadiasl
Abstract
A series of (Epoxy/Polyurethane)/Apple Waste Activated Carbon (EP/PU)/(AWAC) bio composites have been prepared with varying amounts of apple waste activated carbon (AWAC) viz., 0, 2.5, 5, 7.5 and 10 wt %. The prepared bio composites have been characterized for physico-mechanical behaviors and chemical ...
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A series of (Epoxy/Polyurethane)/Apple Waste Activated Carbon (EP/PU)/(AWAC) bio composites have been prepared with varying amounts of apple waste activated carbon (AWAC) viz., 0, 2.5, 5, 7.5 and 10 wt %. The prepared bio composites have been characterized for physico-mechanical behaviors and chemical resistance. The obtained biocomposites have characterized via thermogravimetric analysis (TGA), Differential Scanning Calorimetry (DSC), and Scanning electron microscopy (SEM) to reveal the effect of the presence of the apple waste activated carbon (AWAC) on the properties of the obtained adsorbent. The thermal degradation behaviors of bio composites have been established using TGA thermograms. These results indicate that it is possible with increase the apple waste activated carbon content adsorption of (EP/PU)/(AWAC) is increased. Developed biocomposites from apple waste materials will help to reduce the overall cost of the materials for its demanding applications as insulating material. The as-prepared (EP/PU)/(AWAC) bio-adsorbent removes the cationic dyes from the waste water.
Robab Mohammadi; Milad Alizadehlarijan
Abstract
In this research, Fe3O4 and Fe3O4/Graphene materials were prepared and characterized via different techniques such as X-ray diffractometer (XRD), Vibrating Sample Magnetometer (VSM), and energy-dispersive X-ray spectroscopy (EDX). The efficiency of prepared samples were investigated by elimination of ...
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In this research, Fe3O4 and Fe3O4/Graphene materials were prepared and characterized via different techniques such as X-ray diffractometer (XRD), Vibrating Sample Magnetometer (VSM), and energy-dispersive X-ray spectroscopy (EDX). The efficiency of prepared samples were investigated by elimination of methylene blue as a cationic dye from aqueous solutions via different methods such as adsorption, photodegradation and sonodegradation processes. The results indicated that the degradation rate of methylene blue by Fe3O4/Graphene nanocomposite under sonocatalytic process was considerably higher than the adsorption and photocatalytic procedures. Sonocatalytic degradation of methylene blue by Fe3O4/Graphene nanocomposite could be explained by the mechanisms of hot spots and sonoluminescence. The degradation pathways between sonocatalytic oxidation and methylene blue solution was described. The results showed that the conjugate structure of nitrogen-sulfur heterocyclic material was broken and aromatic ring was oxidized to open the ring. Methylene blue molecules were finally mineralized to H2O and CO2 in the sonocatalytic degradation process. Furthermore, the figures-of-merit based on electric energy consumption (electrical energy per order (EEO)) were estimated in the degradation of methylene blue in the presence of Fe3O4/Graphene nanocomposite. The results showed that less energy is consumed during the sonodegradation of methylene blue in the presence of Fe3O4/Graphene nanocomposite in comparison with photodegradation procedure.
Mohammad Mazloum-Ardakani; Mehrorang Ghaedi; Shaaker Hajati; Behnaz Barazesh
Volume 5, Issue 2 , September 2018, , Pages 17-22
Abstract
Two locally available, cost-effective, renewable biosorbents including the untreated straw of Smyrniopsis Aucheri and untreated leaf of Acer Negundo were used for the removal of Methylene Blue dye. The influence of initial dye concentration on the dye removal was investigated. Isotherm and kinetics ...
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Two locally available, cost-effective, renewable biosorbents including the untreated straw of Smyrniopsis Aucheri and untreated leaf of Acer Negundo were used for the removal of Methylene Blue dye. The influence of initial dye concentration on the dye removal was investigated. Isotherm and kinetics of the biosorption process were studied. The optimum pH was found to be 6 and 5 for Smyrniopsis Aucheri and Acer Negundo, respectively. The optimum biosorbent dosage was found to be 0.3 g for Smyrniopsis Aucheri and 0.5 g for Acer Negundo. The removal of Methylene Blue by Smyrniopsis Aucheri and Acer Negundo occurred during 10 and 15 min, respectively. The quick biosorption using reasonably small amount of such natural and untreated materials is a big advantages of this work for wastewater treatment applications in an environmental friendly way. The Langmuir adsorption isotherm model, was found to be the best applicable one to fit the experimental data. The pseudo-second and pseudo-first order kinetic models were applied well to describe the kinetics of Smyrniopsis Aucheri and Acer Negundo biosorption, respectively.
