نوع مقاله : مقاله پژوهشی کامل
نویسندگان
1 دانشجوی کارشناسی ارشد، شیمی تجزیه، دانشگاه پیامنور، شیراز، ایران.
2 دکترای شیمی تجزیه، استادیار، دانشگاه پیام نور، تهران، ایران.
10.30473/ijac.2026.76089.1329
چکیده
فاضلاب صنایع نساجی به عنوان آلودهترین نوع در میان تمامی بخشهای صنعتی طبقهبندی میشود. در این میان، رنگهای آزو یکی از مهمترین آلایندههایی هستند که اثرات سمی متعددی، بهویژه خاصیت سرطانزایی و جهشزایی دارند. از این رو، توسعه یک فرایند فوتوکاتالیستی قدرتمند، سازگار با محیط زیست و کارآمد برای حذف رنگهای آزو ضروری است. در این مطالعه، نانوذرات فریت کبالت دوپه شده با آلومینیوم (AlCoFe2O4) به روش همرسوبی به عنوان یک فوتوکاتالیست سبز برای تخریب رنگهای آزوی آنیونی و کاتیونی سنتز شدند. نانوذرات سنتز شده با استفاده از تکنیکهای XRD، EDS، DRS، FESEM و VSM مشخصهیابی شدند. نتایج XRD نشان داد که نانوذرات دارای ساختار مکعبی با میانگین اندازه قطر کمتر از ۴۵ نانومتر هستند. میزان پایین پسماند مغناطیسی (Remanent magnetization) و نیروی وادارندگی مغناطیسی (Coercivity) در تحلیل VSM، با خواص مغناطیسی نرم نانوذرات مطابقت داشت. علاوه بر این، خواص مغناطیسی نانوذرات AlCoFe2O4 امکان جداسازی آسان فوتوکاتالیست از محیط واکنش را با استفاده از یک میدان مغناطیسی خارجی فراهم میکند. افزون بر این، جذب بالای AlCoFe2O4 در ناحیه نور مرئی، افزایش عملکرد فوتوکاتالیستی این کاتالیست را تحت تابش نور مرئی امکانپذیر میسازد. آزمونهای فوتوکاتالیستی با استفاده از رنگهای متیل اورانژ (MO) و بیسمارک براون (BB) نشان داد که تخریب به شدت به مقدار pH ) pH بهینه تقریباً ۳ برای MO و ۹ برای BB)، جذب مولکولهای رنگ بر سطح کاتالیست و مقدار دوز کاتالیست (05/0 گرم) وابسته است. تحت شرایط بهینهسازی شده، تخریب MO تحت تابش UV به ۱۰۰% و تخریب BB به ۹۸% رسید. فوتوکاتالیست مذکور عملکرد بالای خود را حداقل در طی پنج چرخه حفظ کرد که نشاندهنده پایداری و قابلیت بازیافت آن است.
کلیدواژهها
موضوعات
[1] N.R. Vaghela and K. Nath. Modelling and multi-objective optimization of continuous indirect electro-oxidation process for RTB21 dye wastewater using ANN-GA approach. Acta Chim. Slov. 69 (2022) 304-315.
[2] S. Findik. Removal of diazo dye Direct Red 28 and tetra azo dye Direct Black 22 using synthesized magnetic kaolin supported zinc ferrite. Acta Chim. Slov. 69 (2022) 336-348. http://dx.doi.org/10.17344/acsi.2021.7289
[3] U. Jayaram and M.A. Azam. Computational molecular modeling studies of some Mycobacterium tuberculosis alanine racemase inhibitors. Acta Chim. Slov. 69 (2022) 393-404. http://dx.doi.org/10.17344/acsi.2021.7267
[4] N.S. Gilani, S.E. Tilami and S.N. Azizi. Adsorption properties of low-cost synthesized nanozeolite L for efficient removal of toxic methylene blue dye from aqueous solution. Acta Chim. Slov. 69 (2022) 458-465. http://dx.doi.org/10.17344/acsi.2022.7350
[5] N.Y. Donkadokula, A.K. Kola, I. Naz and D. Saroj. A review on advanced physico-chemical and biological textile dye wastewater treatment techniques. Rev. Environ. Sci. Biotechnol. 19 (2020) 543-560. https://doi.org/10.1007/s11157-020-09543-z
[6] A. Alhujaily, H. Yu, X. Zhang and F. Ma. Adsorptive removal of anionic dyes from aqueous solutions using spent mushroom waste. Appl. Water Sci. 10 (2020) 1-12. https://doi.org/10.1007/s13201-020-01268-2
[7] A. Ahmadi, R. Foroutan, H. Esmaeili and S. Tamjidi. The role of bentonite clay and bentonite clay@MnFe2O4 composite and their physico-chemical properties on the removal of Cr (III) and Cr (VI) from aqueous media. Environ. Sci. Pollut. Res. 27 (2020) 14044-14057. https://doi.org/10.1007/s11356-020-07756-x
[8] D.A. Yaseen and M. Scholz. Textile dye wastewater characteristics and constituents of synthetic effluents: a critical review. Int. J. Environ. Sci. Technol. 16 (2019) 1193-1226. https://doi.org/10.1007/s13762-018-2130-z
[9] S. Temel, E. Yaman, N. Ozbay and F.O. Gokmen. Synthesis, characterization and adsorption studies of nano-composite hydrogels and the effect of SiO2 on the capacity for the removal of methylene blue dye. J. Serb. Chem. Soc. 85 (2020) 939-952. https://doi.org/10.2298/JSC190517114T
[10] M.D. Khan, A. Singh, M.Z. Khan, S. Tabraiz and J. Sheikh. Current perspectives, recent advancements, and efficiencies of various dye-containing wastewater treatment technologies. J. Water Process Eng. 53 (2023) 103579. https://doi.org/10.1016/j.jwpe.2023.103579
[11] L.D. Paquini, L.T. Marconsini, L.P.R. Profeti, O.S. Campos, D. Profeti and J. Ribeiro. An overview of electrochemical advanced oxidation processes applied for the removal of azo dyes. Braz. J. Chem. Eng. 40 (2023) 623-653. https://doi.org/10.1007/s43153-023-00300-7
[12] H. Solayman, M.A. Hossen, A. Abd Aziz, N.Y. Yahya, K.H. Leong, L.C. Sim, M.U. Monir and K.-D. Zoh. Performance evaluation of dye wastewater treatment technologies: a review. J. Environ. Chem. Eng. 11 (2023) 109610. https://doi.org/10.1016/j.jece.2023.109610
[13] I.A. Shah, M. Bilal, I.W. Almanassra and I. Ihsanullah. A comprehensive review of graphene oxide-based membranes for efficient dye removal from water sources. Sep. Purif. Technol. 330 (2024) 125277. https://doi.org/10.1016/j.seppur.2023.125277
[14] T.Y. Ying, A.A.A. Raman, M.M. Bello and A. Buthiyappan. Magnetic graphene oxide-biomass activated carbon composite for dye removal. Korean J. Chem. Eng. 37 (2020) 2179-2191. https://doi.org/10.1007/s11814-020-0628-9
[15] B. Zhou, Y. Tang, L. Zhao, L. Guo and J. Zhou. Novel Fe3O4–poly (methacryloxyethyltrimethyl ammonium chloride) adsorbent for the ultrafast and efficient removal of anionic dyes. RSC Adv. 11 (2021) 1172-1181. https://doi.org/10.1039/D0RA09296G
[16] Z. Duan, Y. Li, M. Zhang, H. Bian, Y. Wang, L. Zhu and D. Xia. Towards cleaner wastewater treatment for special removal of cationic organic dye pollutants: a case study on application of supramolecular inclusion technology with β-cyclodextrin derivatives. J. Clean. Prod. 256 (2020) 120308. https://doi.org/10.1016/j.jclepro.2020.120308
[17] T. Li, H.L. Song, H. Xu, X.L. Yang and Q.L. Chen. Biological detoxification and decolorization enhancement of azo dye by introducing natural electron mediators in MFCs. J. Hazard. Mater. 416 (2021) 125864. https://doi.org/10.1016/j.jhazmat.2021.125864
[18] E. Danso-Boateng, E. Nyktari, A.D. Wheatley, R.G. Holdich and A.S. Mohammed. Production and characterisation of adsorbents synthesised by hydrothermal carbonisation of biomass wastes. Water Air Soil Pollut. 231 (2020) 1. https://doi.org/10.1007/s42452-021-04273-5
[19] C. Ram, P. Rani, K.A. Gebru and M.G.M. Abrha. Pulp and paper industry wastewater treatment: use of microbes and their enzymes. Phys. Sci. Rev. 5 (2020) 20190050. https://doi.org/10.1515/psr-2019-0050
[20] E. Routoula and S.V. Patwardhan. Degradation of anthraquinone dyes from effluents: a review focusing on enzymatic dye degradation with industrial potential. Environ. Sci. Technol. 54 (2020) 647-664. https://doi.org/10.1021/acs.est.9b03737
[21] K.O. Badmus, J.O. Tijani, E. Massima and L. Petrik. Treatment of persistent organic pollutants in wastewater using hydrodynamic cavitation in synergy with advanced oxidation process. Environ. Sci. Pollut. Res. 25 (2018) 7299-7314. https://doi.org/10.1007/s11356-017-1171-z
[22] H. Fattahimoghaddam, T. Mahvelati-Shamsabadi and B.K. Lee. Efficient photodegradation of rhodamine B and tetracycline over robust and green g-C3N4 nanostructures: supramolecular design. J. Hazard. Mater. 403 (2020) 123703. https://doi.org/10.1016/j.jhazmat.2020.123703
[23] J.E. Kumar, T. Mulai, W. Kharmawphlang, R.N. Sharan and M.K. Sahoo. Experimental studies on the removal of aluminium ions from synthetic aqueous solution by hydroxyapatites. Acta Chim. Slov. 68 (2021) 833-848. http://dx.doi.org/10.17344/acsi.2021.6830
[24] S.P. Goutam, G. Saxena, V. Singh, A.K. Yadav, R.N. Bharagava and K.B. Thapa. Green synthesis of TiO2 nanoparticles using leaf extract of Jatropha curcas L. for photocatalytic degradation of tannery wastewater. Chem. Eng. J. 336 (2018) 386-396. https://doi.org/10.1016/j.cej.2017.12.029
[25] A. Khalil, N.M. Aboamera, W.S. Nasser, W.H. Mahmoud and G.G. Mohamed. Photodegradation of organic dyes by PAN/SiO2-TiO2-NH2 nanofiber membrane under visible light. Sep. Purif. Technol. 224 (2019) 509-514. https://doi.org/10.1016/j.seppur.2019.05.056
[26] Q.U. Ain, U. Rasheed, M. Yaseen, H. Zhang and Z. Tong. Superior dye degradation and adsorption capability of polydopamine modified Fe3O4-pillared bentonite composite. J. Hazard. Mater. 397 (2020) 122758. https://doi.org/10.1016/j.jhazmat.2020.122758
[27] A. Kumar, S.K. Sharma and G. Sharma. Wide spectral degradation of norfloxacin by Ag@BiPO4/BiOBr/BiFeO3 nano-assembly: elucidating the photocatalytic mechanism under different light sources. J. Hazard. Mater. 364 (2019) 429-440. https://doi.org/10.1016/j.jhazmat.2018.10.060
[28] P. Mehdizadeh, Y. Orooji, O. Amiri, M. Salavati-Niasari and H. Moayedi. Green synthesis using cherry and orange juice and characterization of TbFeO3 ceramic nanostructures and their application as photocatalysts under UV light for removal of organic dyes. J. Clean. Prod. 252 (2020) 119765. https://doi.org/10.1016/j.jclepro.2019.119765
[29] A. Saljooqi, T. Shamspur and A. Mostafavi. Synthesis and photocatal
N.S. Mirbagheri and S. Sabbaghi. A natural kaolin/γ‑Fe2O3 composite as an efficient nano-adsorbent for removal of phenol from aqueous solutions. Microporous Mesoporous Mater. 259 (2018) 134-141. https://doi.org/10.1016/j.micromeso.2017.10.007
[30] S. Tabari, A.R. Pourali and E. Nazarzadeh Zare. Magnetic nanoparticles linked to pyridinium hydrotribromide groups as catalysts for selective oxidation of alcohols and protection of alcohols. Acta Chim. Slov. 69 (2022) 271-280. http://dx.doi.org/10.17344/acsi.2021.6761
[31] B. Erdem, S. Erdem and N. Tekin. Cationic surfactant templated synthesis of magnetic mesoporous nanocomposites for efficient removal of light green. Korean J. Chem. Eng. 38 (2021) 1425-1437. https://doi.org/10.1007/s11814-021-0829-x
[32] P.M. Martins, A.C. Lima, S. Ribeiro, S.L. Mendez and P. Martins. Magnetic nanoparticles for biomedical applications: from the soul of the earth to the deep history of ourselves. ACS Appl. Bio Mater. 4 (2021) 5839-5870. https://doi.org/10.1021/acsabm.1c00440
[33] J. Heydaripour, M. Gazi, A.A. Oladipo and H.O. Gulcan. Porous magnetic resin‑g‑chitosan beads for adsorptive removal of phenolic compounds. Int. J. Biol. Macromol. 123 (2019) 1125-1131. https://doi.org/10.1016/j.ijbiomac.2018.11.168
[34] S. Moradi, M. Moradian and H. Naeimi. Efficient one-pot synthesis of 1,4‑dihydropyridines catalyzed by magnetic MnFe2O4 nanoparticles. Acta Chim. Slov. 69 (2022) 349-358. http://dx.doi.org/10.17344/acsi.2021.7238
[35] Y. Peng, G. Ye, Y. Du, L. Zeng, J. Hao, S. Wang and J. Zhou. Fe3O4 hollow nanospheres on graphene oxide as an efficient heterogeneous photo-Fenton catalyst for the advanced treatment of biotreated papermaking effluent. Environ. Sci. Pollut. Res. 28 (2021) 39199-39209. https://doi.org/10.1007/s11356-021-13458-9
[36] F. Mostaghni, H. Shafiekhani and N. Madadi Mahani. A facile synthesis of bioactive five‑ and six‑membered N‑heterocyclic aromatic compounds using AlCoFe2O4 as a green catalyst. Acta Chim. Slov. 69 (2022) 91-97. https://doi.org/10.17344/acsi.2021.7021
[37]H.N. Tran, Y.F. Wang, S.J. You and H.P. Chao. Insights into the mechanism of cationic dye adsorption on activated charcoal: the importance of π–π interactions. Process Saf. Environ. Prot. 107 (2017) 168-180. https://doi.org/10.1016/j.psep.2017.02.010
[38] M. Hosseini. Visible-light-assisted decontamination of sertraline in water using a Co3O4/g-C3N4 nanocomposite photocatalyst. Environ. Sci. Pollut. Res. 32 (2025) 20441–20460. https://doi.org/10.1007/s11356-025-36848-9
[39] M. Naz. A. Rafiq. M. Ikram. A. Haider. S.O.A. Ahmad. J. Haider and S. Naz. Elimination of dyes by catalytic reduction in the absence of light: A review. J. Mater. Sci. 56 (2021). https://doi.org/10.1007/s10853-021-06279-1
[40] M. Panahimehr. S. Asghari. M. Hosseini and A. Mojaddami. Pd/ZnMn2O4/chitosan nanobiocatalyst: A sustainable solution for sunlight-enhanced photocatalytic degradation of Congo red dye. J. Mol. Struct. (2025). https://doi.org/10.1016/j.molstruc.2025.143339
[41] H. Ma. A. Kong. Y. Ji. B. He. Y. Song and J. Li. Ultrahigh adsorption capacities for anionic and cationic dyes from wastewater using only chitosan. J. Clean. Prod. (2018). https://doi.org/10.1016/j.jclepro.2018.12.217
)