Iranian Journal of Analytical Chemistry

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Determination of Diazinon in Environmental Samples Using Modified Multi-Walled Carbon Nanotubes as Pipette-Tip Solid Phase Extraction Sorbent

Document Type : Full research article

Authors

1 Department of Environmental Health Engineering, Faculty of Health, Zabol University of Medical Sciences, Zabol, Iran

2 Department of Chemistry, Faculty of Sciences, University of Sistan and Baluchestan, Zahedan, Iran

3 Department of Material Engineering, University of Sistan and Baluchestan, Zahedan, Iran

4 Department of Occupational Health Engineering, Kerman University of Medical Sciences, Kerman, Iran

Abstract

In this work, a microextraction technique based on pipette tip solid-phase extraction was used for preconcentration and determination of diazinon. Carbon nanotube functionalized by zinc sulfide and ethylene glycol was used as sorbent. Determination of diazinon was performed using high performance liquid chromatography and UV detection. Important parameters that influence the extraction efficiency (i.e. pH, amount of adsorbent, extraction time, salt addition, volumes of sample and eluting solvent and number of aspirating/dispensing cycles for both solvent and sample) were investigated and optimized. Results were showed that method was validated over the range of 0.50 - 100.0 µg L-1. Repeatability was satisfactory, bellow 3.78% for 5 replicate measurements of 20 µg L-1 of diazinon. The limit of detection of this method is 0.03 µg L-1 with an enrichment factor of 100 and short extraction time of 8.5 min, which confirmed suggested method is a reliable and accurate for extraction and preconcentration of diazinon.

Keywords

References
 
[1]     M.R. Sohrabi, S. Jamshidi and A. Esmaeilifar, Cloud point extraction for determination of Diazinon: Optimization of the effective parameters using Taguchi method, Chemom. Intell. Lab. Syst. 110 (2012) 49–54.
[2]     C. PadrnSanz, R. Halko, Z. Sosa Ferrera and J.J. Santana Rodriguez, Micellar extractionof organophosphorus pesticides and their determination by liquid chromatography, Anal. Chim. Acta. 524 (2004) 265–270.
[3]     C. Aprea, C. Colosio, T. Mammone, C. Minoia and M. Maroni, Biological monitoring of pesticide exposure: a review of analytical methods, J. Chromatogr. B 769 (2002) 191–219.
[4]     H. Bagheri, A. Es’haghi and N.Mesbahi, A high-throughputapproach for the determination of pesticide residues in cucumber samples using solid-phase microextraction on 96-well plate, Anal. Chim. Acta, 740 (2012) 36–42.
[5]     B. Albero, C. Sa´ nchez-Brunete and J.L. Tadeo, Multiresidue determination of pesticides in juice by solid-phase extraction and gas chromatography–mass spectrometry, Talanta 66 (2005) 917–924.
[6]     W. Guan, Z. Li, H. Zhang, H. Hong, N. Rebeyev, Y. Ye and Y. Ma, Amine modified rapheme as reversed-dispersive solid phase extraction materials combined with liquid chromatography–tandem mass spectrometry for pesticide multi-residue analysis in oil crops, J. Chromatogr. A 1286 ( 2013) 1–8.
[7]     A. Melo, S.C. Cunha, C. Mansilha, A. Aguiar, O. Pinho and I.M. Ferreira, Monitoring pesticide residues in greenhouse tomato by combining acetonitrile-based extraction with dispersive liquid–liquid microextraction followed by gas-chromatography–mass spectrometry, Food Chem. 135 (2012) 1071–1077.
[8]     S. Berijani, Y. Assadi, M. Anbia, M. Hosseini and R.M. Aghaee, Dispersive liquid–liquid microextraction combined with gas chromatography–flame photometric detection very simple, rapid and sensitive method for the determination of organophosphorus pesticides in water, J. Chromatogr. A.1123 ( 2006) 1–9.
[9]     J. Chen, C. Duan and Y. Guan, Sorptive extraction technique in sample preparation for organophosphorus pesticide in complex matrices, J. Chromatogr. B. 878 (2012) 1216–1225.
[10] T. Kumazawa, C. Hasegawa, S. Uchigasaki, X. Lee, O. Suzuki and K. Sato, Quantitativedetermination of phenothiazine derivatives in human plasma using monolithic silica solid-phase extraction tips and gas chromatography–mass spectrometry, J. Chromatogr. A. 1218 (2012) 2521–2527.
[11] C. Hasegawa, T. Kumazawa, X.P. Lee, A. Marum, N. Shinmen, H. Seno and K. Sato, Pipette tip solid-phase extraction and gas chromatography-mass spectrometry for the determination of methamphetamine and amphetamine in human whole blood, Anal. Bioanal. Chem. 389 (2007) 563−570.
[12] C. Hasegawa, T. Kumazawa, S. Uchigasaki, X. P. Lee, K. Sato, M. Terada and K. Kurosaki, Determination of dextromethorphan in human plasma using pipette tip solid-phase extraction and gas chromatography-mass spectrometry, Anal. Bioanal. Chem. 401 (2011) 2215−2223.
[13] T. Kumazawa, C. Hasegawa, X.P. Lee, A. Marumo, N. Shimmen, A. Ishii, H. Seno and K.  Sato, Pipette tip solid-phase extraction and gas chromatography-mass spectrometry for thedetermination of mequitazine in human plasma, Talanta 70 (2006) 474−478.
[14] S.B. Deng, Q.Y. Zhang, Y. Nie, H.R. Wei, B.  Wang and J. Huang, Sorption mechanisms of perfluorinated compounds on carbon nanotubes, Environ. Pollut. 168 (2012) 138–44.
[15] J.E.N. Dolatabadi, Y. Omidi and D. Losic, Carbon nanotubes as an advanced drug and gene delivery nano system, Curr. Nanosci. 7 (2011) 297–314.
[16] G.D. Sheng, D.D. Shao, X.M. Ren, X.Q. Wang, J.X. Li and Y.X. Chen, Kinetics and thermodynamics of adsorption of ionizable aromatic compounds from aqueous solutions by as-prepared and oxidized multiwalled carbon nanotubes, J. Hazard. Mater.  178 (2010) 505–516.
[17] X. Liu, M. Wang, S. Zhang and B. Pan, Application potential of carbon nanotubes in water treatment: A review, J. Environ. Sci. 25 (2013) 1263–1280.
[18] A. Naeimi, A. MasoudArab. M. ShafieeAfarani and A.R. Gardeshzadeh, In situ synthesis and electrophoretic deposition of CNT–ZnS:Mn luminescentnanocompo-sites, J. Mater. Sci. Mater Electron. 26 (2015) 1403–1412.
[19] P. Toledo Netto, O.J. Teixeira Júnior, J.L.V. de Camargo, M. LúciaRibeiro and M.R.R.de Marchi, A rapid, environmentally friendly, and reliable method for pesticide analysis in high-fat samples, Talanta 101 (2012) 322–329.
[20] H. Guan, W.E. Brewer, S.T. Garris and S.L. Morgan, Disposable pipette extraction for the analysis of pesticides in fruit and vegetables using gas chromatography/mass spectrometry, J. Chromatogr. A. 1217 (2010) 1867–1874.
[21] N. Sun, Y. Han, H. Yan and Y. Song, An in situ immobilized pipette tip solid phase microextraction method based on molecularly imprinted polymer monolith for the selective determination of difenoconazole in tap water and grape juice, J. Chromatogr. B 951(2014) 104–109.
[22] M. Kaykhaii and M. Sargazi, Comparison of two novel in-syringe dispersive liquid–liquid microextraction techniques for the determination of iodide in water samples using spectrophotometry, Spectrochim. Acta, Part A 121( 2014)173–179.
[23] P.G. Su and S.D. Huang, Determination of organophosphorus pesticides in water by solid-phase microextraction, Talanta 49 (1999) 393-397.
[24] H. Katsumata, T. Matsumoto, S. Kaneco, T. Suzuki and K. Ohata, Preconcentration of Diazinon using multiwalled carbon nanotubes as solid-phase extraction adsorbents, Microchem. J. 88 (2008) 82–86.
[25] B. Maddah and J. Shamsi, Extraction and preconcentration of trace amounts of diazinon and fenitrothion from environmental water by magnetite ctadecylsilane nanoparticles, J. Chromatogr. A 1256 ( 2012) 40– 45.
[26] S. Samadia, H. Sereshtia and Y. Assadi, Ultra-preconcentration and determination of thirteen organophosphorus pesticides in water samples using solid-phase extraction followed by dispersive liquid–liquid microextraction and gas chromatography with flame photometric detection,  J. Chromatogr. A 1219 (2012) 61–65.             
Iranian Journal of Analytical Chemistry
Volume 4, Issue 2 - Serial Number 2
September 2017
Pages 10-16
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