Synthesis and Characterization of Graphene Oxide-Melamine (GO-M) Nano Composite and Poly (Styrene –Alternative – Maleic Anhydride) -Melamine (SMA-M) Using for Removing Lead (II) Ions from Aqueous Solutions.

Khodavirdilo, Bakhtiar; Samadi, Naser; Ahari Salmasi, Marzieh

doi:10.30473/ijac.2020.39487.1127

Document Type : Full research article

Authors

¹ Department of Chemistry, Faculty of Science, University of Guilan, University Campus2, Rasht, Iran.

² Department of Analytical Chemistry, Faculty of Chemistry, Urmia University, Urmia, Iran

³ Department of Chemistry, Faculty of Science, University of Azarbaijan Shahid Madani,Tabriz, Iran

https://doi.org/10.30473/ijac.2020.39487.1127

Abstract

In this study a new method by using graphene oxide (GO) Nano sheets-melamine composites and derivation of Poly (Styrene –alternative- Maleic Anhydride) (SMA), (SMA+Melamine) (SMA-M) were presented as Sorbents for the elimination of Lead ions from aqueous solutions. The adsorbents have the sufficiency to adsorb the Lead ions. Through the immobilization of melamine onto GO Nano sheets, the desired composite was synthesized and identified by field emission scanning electron microscopy (FE-SEM), Fourier transform infrared (FT-IR) spectroscopy and absorption atomic spectroscopy (AAS) techniques. The various experimental parameters such as pH and concentration of the aqueous solution of Lead (II) ion, the content of the Lead (II) ion the grapheme oxide-Melamine and SMA-M have been optimized. It was shown that the uptake efficiency of Lead (II) ion considerably increased after immobilization of Melamine on the GO Nano sheets and SMA.

Keywords

20.1001.1.23832207.2020.7.1.9.0

References

[1] A.M.M. Vargas, C.A. Garcia, E.M. Reis, E. Lenzi, W.F. Costa and V.C. Almeida, NaOH-activated carbon from flamboyant (Delonix regia) pods: optimization of preparation conditions using central composite rotatable design, Chem. Eng. J. 162 (2010) 43–50.

[2] K. Gergova and S. Eser, Effects of activation method on the pore structure of activated carbons from apricot stones, Carbon 34 (1996) 879–888.

[3] D. Savova, E. Apak, E. Ekinci, F. Yardım, N. Petrov, T. Budinova, M. Razvigorova and V. Minkova, Biomass conversion to carbon adsorbents and gas, Biomass Bioenergy 21 (2001) 133–142.

[4] W. Heschel and E. Klose, On the suitability of agricultural byproducts in the manufacture of granular activated carbon, Fuel, 74 (1995) 1786–1791.

[5] I.A.W. Tan, A.L. Ahmad and B.H. Hameed, Optimization of preparation conditions for activating carbons from coconut husk using response surface methodology, Chem. Eng. J. 137 (2008) 462–470.

[6] H.M. Mozammel, O. Masahiro and S.C. Bahattacharya, Activated charcoal from coconut shell using ZnCl2 activation, Biomass Bioenergy 22 (2002) 397–400.

[7] Z. Hu, M.P. Srinivasan and N. Yaming, Novel activation process for preparing highly microporous and mesoporous activated carbons, Carbon 39 (2001) 877–886.

[8] K. Gergova, N. Petrov and S. Eser, Adsorption properties and microstructure of activated carbons produced from agricultural by-products by steam pyrolysis, Carbon 32 (1994) 693–702.

[9] M.M. Sabio and F.R. Reinoso, Role of chemical activation in the development of carbon porosity, Colloids Surf. 241 (2004) 15–25.

[10] A. Gurses, C. Dogar, S. Karaca, M. Ackyldz and R. Bayrak, Production of granular activated carbon from waste Rosa canina sp. seeds and its adsorption characteristics for dye, J. Hazard.Mater. 131 (2006) 254–259.

[11] C. Sudhersan and J. Hussain, In vitro propagation of amultipurpose tree, Ziziphus spina-christi (L.), Desf, Turk. J. Bot. 27 (2003) 167–171.

[12] E. Lev and Z. Amar, Ethnopharmacological survey of traditional drugs sold in Israel at the end of the 20th century, J. Ethnopharmacol. 72 (2000) 191–205.

[13] N. Samadi, R. Ansari, B.Khodavirdilo,Removal of Manganese Ions From Aqueous Solutions Using Polymers Derivations of Poly (Styrene-Alt- Maleic Anhydride), Iran J. Anal.Chem.3 (2016) 127-136.

[14] A.A. Shahat, L. Pieters, S. Apers, N.M. Nazeit, N.S. Abdel-Azim, D.V. Berghe and A.T. Vlietinck, Chemical and biological investigation on Ziziphus spina-christi L, Phytother. Res. 15 (2001) 593–597.

[15] W. Feng-Chin, T. Ru-Ling and J. Ruey-Shin, Preparation of highly microporous carbons from fir wood by KOH activation for adsorption of dyes and phenols from water, Sep. Purif. Technol. 47 (2005) 10–19.

[16] Z. Hu and M.P. Srinivasan, Preparation of high-surface-area activated carbons from coconut shell, Microporous Mesoporous Mater. 27 (1999) 11–18.

[17] S. Braunauer, P. Emmette and E. Teller, Adsorption of gases in multimolecular layers, J. Am. Chem. Soc. 60 (1938) 309–319.

[18] V. Gomez-Serrano, J. Pastor-Villegas, C.J. Duran-Valle and C. Valenzuela-Calahorro, Heat treatment of Rockrose char in the air.Effect on surface . hemistry and porous texture, Carbon 34 (1996) 533–538.

[19] M.S. Solum, R.J. Pugmire, M. Jagtoyen and F. Derbyshire, Evolution of carbon structure in chemically activated wood, Carbon 33 (1995) 1247–1254.

[20] J. Pastor-Villegas, C. Valenzuela-Calahorro, A. Bernalte-Garcia and V. Gomezserrano, Characterisation study of char and activated carbon prepared from raw and extracted rockrose, Carbon 31 (1993) 1061–1069.

[21] H.E.S. Amjad, P.N. Alan, K.A.D. Hafid, P. Suki and C. Neil, Characterization of activated carbon prepared from a single cultivar of Jordanian Olive stones by chemical and physicochemical techniques, J. Anal. Appl. Pyrol. 71 (2004) 151–164.

[22] J.C.P. Vaghetti, E.C. Lima, B. Royer, B.M. da Cunha, N.F.Cardoso, J.L. Brasil and S.L.P. Dias, Pecan nutshell, as biosorbent to remove Cu (II), Mn (II) and Pb (II) from aqueous solutions, J. Hazard. Mater. 162 (2009) 270–280.

[23] . Zheng, X.M. Li, F. Wang, Q. Yang, P. Deng, Adsorption removal of cadmium and copper from aqueous solution by Areca-a food waste, J. Hazard. Mater. 157(2008) 490-495.

[24] M. J. Soltanianfard, A. Firoozadeh, Synthesis and Characterization of Copper (II) -OxideNano particles from Two Cu (II) Coordination Polymers, J. Sci. I.R. Iran 27 (2016) 113 - 117.

[25] A. Abbasi, M.Gharib and M. Najafi, Preparation of ZnO Nanocrystals with Desired Morphology from Coordination Polymers through a Solid-state Decomposition Route, J. Sci. I.R. Iran 27 (2016) 217 – 221.

[26] M.M. Johns, W.E. Marshall and C.A. Toles, Agricultural byproducts as granular activated carbons for adsorbing dissolved metals and organics, J. Chem. Technol. Biotechnol. 71 (1998) 131–140.

[27] Y. Sun and P.A. Webley, Preparation of activated carbons from corn cob with large specific surface area by a variety of chemical activators and their application in gas storage, Chem. Eng. J. 162 (2010) 883–892.

[28] N. Samadi, R. Ansari, B.Khodavirdilo,Synthesized Nano Particle Derivation of Poly (Styrene -Alternative-Maleic Anhydride) for the Removal of the Silver (I) Ions From Aqueous Solutions, Iranian, J. Anal.Chem.4 (2017) 50-60.

[29] B. Khodavirdilo, N. Samadi, R. Ansari, Synthesis of Graphene Oxide-Melamine–Thio Oxalic acid Nanocomposite and its application in the elimination of Mercury (II) ions. Iran. Chem. Commun. 7 (2019) 71-78.

Iranian Journal of Analytical Chemistry

Synthesis and Characterization of Graphene Oxide-Melamine (GO-M) Nano Composite and Poly (Styrene –Alternative – Maleic Anhydride) -Melamine (SMA-M) Using for Removing Lead (II) Ions from Aqueous Solutions.

References

References

Volume 7, Issue 1 - Serial Number 13
March 2020
Pages 70-77

Synthesis and Characterization of Graphene Oxide-Melamine (GO-M) Nano Composite and Poly (Styrene –Alternative – Maleic Anhydride) -Melamine (SMA-M) Using for Removing Lead (II) Ions from Aqueous Solutions.

References

References

Volume 7, Issue 1 - Serial Number 13March 2020Pages 70-77

Volume 7, Issue 1 - Serial Number 13
March 2020
Pages 70-77