نوع مقاله : مقاله پژوهشی کامل
نویسنده
گروه شیمی، دانشکده علوم پایه، دانشگاه بنها، بنها، مصر
چکیده
یک حسگر نوری کاملاً انتخابی، با استفاده از واکنشگر حساس 5-(2و4دی متیل فنیل آزو)-6- پیریمیدین-2و 4- دی ان (DMPAHPD) در یک فیلم نازک سل-ژلی سیلیسی بر روی شیشه، برای تعیین یون V(IV) تهیه شد. فیلم نازک با استفاده از تترااتوکسی سیلان به عنوان پیش ماده، سل ژل با 2.5=pH، آب:آلکوکسید به نسبت 4:1 و DMPAHPD با غلظت M4-10Í2.5 طراحی گردید. اثر پارامترهای سل-ژل بر روی رفتار حسگر بررسی شد. حسگر طراحی شده برای شناسایی یون های V(IV) با انتخاب پذیری بالا در رنج خطی (ng mL−1) 145-5.0 و حد تشخیص (ng mL−1) 1.35 مورد استفاده قرار گرفت. تکرار پذیری روش با انحراف استاندارد نسبی % 1.75 و % 1.02 برای غلظت های 20 و 70 نانو گرم بر میلی لیتر V(IV) با زمان پاسخ دهی 2 دقیقه بدست آمد. کل وانادیم بعد از کاهش V(V) به V(IV) توسط آسکوربیک اسید تعیین گردید. مقدار V(V) بعد از کم کردن غلظت V(IV) از غلظت کل وانادیم تخمین زده شد. بررسی تداخلات، انتخاب پذیری خوبی را برای V(IV) با استفاده از DMPAHPD فرورفته در ماتریس سل-ژل نشان داد. حسگر پیشنهادی در مقایسه با سایر حسگرها نتایج خوبی را در تعیین وانادیم در نمونه های محیطی مختلف از خود نشان داد.
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