Complexation and Thermodynamic Studies of a New Schiff base Ligand with Some Metallic ions in Nonaqueous Solvents by Conductometric Method

Payehghadr, Mahmood; Hashemi, Seied Ebrahim; Eshaghi, Zarin; Kargar, Hadi

doi:10.30473/ijac.2021.59278.1187

Document Type : Full research article

Authors

¹ Department of Chemistry, Payame Noor University, PO Box 19395-4697, Tehran, Iran

² Department of Chemical Engineering, Ardakan University, P. O. Box: 184, Ardakan, Yazd, Iran

https://doi.org/10.30473/ijac.2021.59278.1187

Abstract

The complexation reactions between N-N′-Bis(5-bromo-2-hydroxybenzylidene)-2,2-dimethylpropane-1,3-diamine Schiff base ligand and Ag⁺, Cd²⁺, Co²⁺, Cu²⁺, Hg²⁺, Ni²⁺, and Zn²⁺ ions were studied conductometrically in acetonitrile, dimethylformamide, ethanol, and methanol solvents at 5, 10, 15, and 25ºC. The formation constants of the resulting ML and M₂L complexes were calculated from the computer fitting of the molar conductance-mole ratio data at different temperatures. The selectivity of the Schiff base ligand to the cations is depended the nature of the solvent. At 25ºC in acetonitrile solvent, the stability of the resulting complexes varied in the order Hg²⁺ > Ag⁺ > Cd²⁺ > Cu²⁺> Co²⁺ > Zn²⁺ > Ni²⁺. It was found that the stability of the resulting complexes decreased with increasing the solvation ability of the solvent. The values of the thermodynamic parameters (ΔH°, ΔS° and ΔG°) for complexation reactions were obtained from the temperature dependence of the stability constants values (log K_f) using the Van’t Hoff plots. In most cases, the complexes were found to be an enthalpy and entropy stabilized.

Keywords

20.1001.1.23832207.2020.7.2.8.1

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[51] S. Ahmadzadeh, A. Kassim, M. Rezayi, G.H. Rounaghi, Molecules, 2011, 16, 8130–8142.

Complexation and Thermodynamic Studies of a New Schiff base Ligand with Some Metallic ions in Nonaqueous Solvents by Conductometric Method

References

References

[1] A. Golcu, M. Tumer, H. Demirelli, R.A. Wheatley, Inorg. Chim. Acta, 2005, 358, 1785-1797.

[2] R. Biswas, D. Brahman, B. Sinha, J. Serb. Chem. Soc., 2014, 7, 1263–1277.

[3] M. Payehghadr, A.A. Babaei, L. Saghatforoush, F. Ashrafi, Afr. J. Pure Appl. Chem., 2009, 3, 092-097.

[4] T. Katsuki, Coord. Chem. Rev., 1995, 140, 189 -214.

[5] C.O. Ugochukwu, Y. Gultneh, R. Otchere, R.J. Butcher, Inorg. Chem. Commun., 2018, 97, 1-6.

[6] S. Di Bella, Chem. Soc. Rev., 2001, 30, 355-366.

[7] E. Jalalvandi, L.R. Hanton, S.C. Moratti, Eur. Polym. J., 2017, 90, 13-24.

[8] P.R. Surati, B.A. Shah, Chem. Pap., 2015, 69, 368–375.

[9] K. Tanaka, R. Shimpoura, M.R. Caira, Tetrahedron Lett., 2010, 51, 449-452.

[10] J. Zhao, Y. Niu, B. Ren, H. Chen, S. Zhang, J. Jin, Y. Zhang, Chem. J., 2018, 347, 574-584.

[11] Y. Yu, S. Lei, Encyclopedia of Interfacial Chemistry, Surface Science and Electrochemistry, 2018, Elsevier.

[12] Z. Parsaee, N. Karachi, R. Razavic, Ultrason. Sonochem., 2018, 47, 36-46.

[13] M.F. Cheira, A.S. Orabi, M.A. Hassanin, S.M.Hassan, Chem. Data. Collect., 2018, 13–14, 84–103.

[14] A. Shokrollahi, M. Ghaedi, M. Montazerozohori, A.H. Kianfar, H.N. Khanjari, S. Noshadi, S. Joybar, E-J. Chem., 2011, 8, 495-506.

[15] M. Joshaghani, M.B. Gholivand, F. Ahmadi, Spectrochim. Acta, Part A, 2008, 70, 1073–1078.

[16] G.H. Rounaghi, M. Mohajeri, S. Tarahomi, Asian J. Chem., 2009, 21, 4861- 4870.

[17] G. Gritzner, J. Mol. Liq., 1997, 73-74, 487-500.

[18] M. Munakta, S. Kitagawa, Inorg. Chim. Acta, 1990, 169, 225-234.

[19] B.O. Strasser, A.I. Popov, J. Am. Chem. Soc., 1985, 107, 7921–7924.

[20] V. Gutmann, D. Wyehera, Inorg. Nucl. Chem. Lett., 1966, 2, 257-260.

[21] M. Montazerozohori, S.A.R. Musavi, S. Joohari, Res. J. Recent Sci., 2012, 1, 9-15.

[22] I.J. Chang, M.G. Choi, Y.A. Jeong, S.H. Lee, S. Chang, Tetrahedron Lett., 2017, 58, 474-477.

[23] D. Singhal, A.K. Singh, A. Upadhyay, Mater. Sci. Eng. C, 2014, 45, 216–224.

[24] F. Nourifard, M. Payehghadr, Int. J. Environ. Anal. Chem., 2016, 96, 552-567.

[25] F. Nourifard,, M. Payehghadr, M. Kalhor, A. Nezhadali, Electroanalysis, 2015, 27, 2479–2485.

[26] M. Ocak, N. Gumrukcuoglu, U. Ocak, H. Buschmann, E. Schollmeyer, J. Solution Chem., 2008, 37, 1489–1497.

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[31] G.H. Rounaghi, F. Mofazzeli, J. Incl. Phenom. Macrocycl. Chem., 2005, 51, 205–210.

[32] A. Nezhadali, Gh. Taslimi, Alexandria Eng. J., 2013, 52, 797–800.

[33] K. Suhud, L.Y. Heng, M. Rezayi, A.A. Al-abbasi, S.A. Hasbullah, M. Ahmad, M.B. Kassim, J. Solution Chem., 2015, 44, 181–192.

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[35] M.K. Amini, M. Shamsipur, Inorg. Chim. Acta, 1991, 183, 65–69.

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[37] V.A. Nicely, J.L. Dye, J. Chem. Educ., 1970, 48, 443-448.

[38] L. Lampugnani, L. Meites, P. Papoff, T. Rotunno, Anal. Chim. Acta, 1987, 194, 77-89.

[39] L.G. Sillen, B. Warnquist, Ark. Kemi., 1968, 31, 377- 390.

[40] D.J. Leggett, W.A.E. McBryde, Anal. Chem., 1975, 47, 1065–1070.

[41] R.M. Alcock, F.R. Hartley, D.E. Rogers, J. Chem. Soc. Dalton Trans., 1978, 9, 115- 123.

[42] N. Maleki, B. Haghighi, A. Safavi, Microchem. J., 1999, 62, 229–236.

[43] J.A. Nelder, R. Meadf, Comp. Jour., 1965, 7, 308–313.

[44] A.F. Cotton, G. Wilkinson, Advanced Inorganic Chemistry, 1972, John Wiley and sons, New York.

[45] M. Rahimi-Nasrabadi, F. Ahmadi, S.M. Pourmortazavi, M.R. Ganjali, K. Alizadeh, J. Mol. Liq., 2009, 144, 97–101.

[46] G.H. Rounaghi, Z. Eshaghi, E. Ghiamati, Talanta, 1997, 44, 275-282.

[47] V. Gutmann, Coordination Chemistry in Non-Aqueous Solutions, 1968, Springer–Verlag.

[48] M. Payehghadr, A. Zamani, Asian J. Chem., 2009, 21, 3788-3798.

[49] M.K. Amini, M. Shamsipur, J. Solution Chem., 1992, 21, 275-278.

[50] M. Payehghadr, S.E. Hashemi, J. Incl. Phenom. Macrocycl. Chem., 2017, 89, 253–271.

[51] S. Ahmadzadeh, A. Kassim, M. Rezayi, G.H. Rounaghi, Molecules, 2011, 16, 8130–8142.

Volume 7, Issue 2 - Serial Number 14September 2020Pages 67-74

Volume 7, Issue 2 - Serial Number 14
September 2020
Pages 67-74