نوع مقاله : مقاله پژوهشی کامل
نویسندگان
1 گروه شیمی، دانشکده علوم، دانشگاه زابل، زابل، ایران
2 گروه پژوهشی شیمی، پژوهشکده شیمی و پتروشیمی، پژوهشگاه استاندارد، کرج، ایران
چکیده
هیدروژن پراکسید (H2O2) کاربرد گسترده‌ای در صنایع مختلف نظیر نساجی، دارویی، بالینی و مواد غذایی دارد. هیدروژن پراکسید به‌طور معمول در غلظت حدود 6% استفاده می‌شود، اما در غلظت بالاتر می‌تواند اکسید کننده، خورنده و سمی باشد. در این تحقیق، یک حسگر الکتروشیمیایی جدید مبتنی بر نانوکامپوزیت هیدروکسید لایه‌ای دوگانه فلزات Cu/Fe تثبیت شده برروی بستر مغناطیسی با موفقیت ساخته شده و برای تشخیص H2O2 مورد استفاده قرار می‌گیرد. جهت بررسی ساختار و ویژگی نانوکامپوزیت تهیه شده از میکروسکوپ الکترونی روبشی، پراش اشعه ایکس، ولتامتری چرخه‌ای و ولتامتری پالس تفاضلی استفاده شد. سپس نانوکامپوزیت برروی الکترود کربن شیشه‌ای تثبیت و فعالیت الکتروکاتالیستی آن در احیاء H2O2 مورد بررسی قرار گرفت. عوامل موثر بر فعالیت الکتروکاتالیستی (مقدار اصلاح‌گر، pH محلول و زمان آنالیز) بررسی و بهینه‌سازی شد. تحت شرایط بهینه، هیدروژن پراکسید یک جریان احیایی خطی از خود نشان داد. هم‌چنین حدتشخیص 3 میکرومولار و تکرار پذیری حسگر تهیه شده در محدوده 2 تا 400 میکرومولار به دست آمد. در نهایت حسگر مربوطه به‌صورت موفقیت آمیز برای تعیین هیدروژن پراکسید با محاسبه بازیابی در نمونه شیر مورد مطالعه قرار گرفت.
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