نوع مقاله : مقاله مروری
نویسندگان
1 گروه شیمی، دانشگاه پیام نور، صندوق پستی 4667-16365 ،تهران، ایران
2 داروسازی طلای سبز طوبی، تهران، ایران؛ دانشکده طب سنتی، دانشگاه علوم پزشکی تهران، تهران، ایران
3 استادیار بخش شیمی دانشگاه آزاد اسلامی واحد کازرون، ایران
چکیده
در این تحقیق، عصاره curcuma zedoaria به عنوان بازدارنده خوردگی استیل نرم در محلول 5/0 مولار سولفوریک اسید به روش های متداول کاهش وزن، طیف سنجی الکتروشیمیایی امپدانس و پلاریزاسیون در دمای °C25 مورد بررسی قرار گرفت. بیشترین درصد بازدارندگی برای غلظت 5/0 گرم بر لیتر از عصاره curcuma zedoaria به دست آمد. نتایج روش پلاریزاسیون نشان داد که عصاره curcuma zedoaria به عنوان بازدارنده مختلط عمل می کند. بررسی زمان غوطه وری استیل نرم به روش کاهش وزن نشان داد که با افزایش مدت زمان غوطه وری اثر بازدارندگی در غلظت های کم عصاره curcuma zedoaria کاهش می یابد اما در غلظت های بیشتر از عصاره curcuma zedoaria (غلظت 0/1 گرم بر لیتر) اثر بازدارندگی با گذشت زمان تقریبا ثابت می ماند. بررسی اثر دما بر عملکرد عصاره curcuma zedoaria به روش الکتروشیمیایی پلاریزاسیون در محدوده دمایی °C 65- 35 نشان دهنده کاهش در درصد بازدارندگی با افزایش دما است. جذب مولکول های عصاره curcuma zedoaria بر سطح استیل نرم در تمام دماهای مورد بررسی از هم دمای جذب لانگمویر پیروی می کند. با استفاده از نتایج محاسبات سینتیکی و ترمودینامیکی جذب مولکول های عصاره curcuma zedoaria بر سطح استیل نرم از نوع جذب فیزیکی مشاهده شد.
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