نوع مقاله : مقاله پژوهشی کامل
نویسندگان
1 گروه شیمی، دانشکده علوم، دانشگاه فردوسی مشهد، مشهد، ایران
2 گروه شیمی، دانشکده علوم، دانشگاه پیام نور، تهران، ایران
چکیده
این مطالعه شناسایی و تعیین فتالات استرها در نمونه های آرایشی را مورد توجه قرار داده است. از استخراج فاز جامد پراکنده قبل از آنالیز کروماتوگرافی مایع با عملکرد بالا ، برای استخراج آنالیت استفاده شد. جاذب جامد برای استخراج، پلی اتیلن گلیکول بود که روی نانوذرات اکسید مس پیوند زده شد (PEG-g-CuO-NPs). این جاذب ابتدا سنتز و سپس با میکروسکوپ الکترونی روبشی (SEM) ، پراکندگی انرژی اشعه ایکس (EDX) و طیف سنجی مادون قرمز با تبدیل فوریه (FT-IR) مشخصه یابی شد و سپس برای استخراج آنالیت ها به کار گرفته شد. شرایط استخراج مانند مقدار جاذب ، نوع و حجم حلال واجذب ، زمان استخراج و واجذب و pH محلول نمونه بهینه شد. اعتبار سنجی روش انجام شد و در شرایط بهینه دامنه های خطی 0.005-4 میکروگرم بر میلی لیتر با ضریب همبستگی (R2) در محدوده 0.9914-0.9962 بدست آمد. حد تشخیص ها بین (LODs) 0.0025-0.005 میکروگرم بر میلی لیتر و تکرارپذیری قابل قبول (RSD های زیر 6.45٪ ، 5 n=) بدست آمد. کاربرد روش پیشنهادی با استخراج فتالات ها در شامپوی بچه و شوینده ی بدن مورد بررسی قرار گرفت که نتایج رضایت بخشی حاصل شد.
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