Sayed Zia Mohammadi; Sareh Torabian; Somayeh Tajik
Abstract
In the present research, an effective adsorbent as titled multiwall carbon nanotube/ZnCo- Zeolite imidazole frameworks (MWC/ZIF) was prepared and used for removal of Pb(II) ion from effluent samples. After separating the adsorbent from the solution, the amount of Pb(II) ion in the solution was measured ...
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In the present research, an effective adsorbent as titled multiwall carbon nanotube/ZnCo- Zeolite imidazole frameworks (MWC/ZIF) was prepared and used for removal of Pb(II) ion from effluent samples. After separating the adsorbent from the solution, the amount of Pb(II) ion in the solution was measured using an atomic absorption device. Based on this, various experimental parameters effective on lead removal including pH, ionic strength, time, temperature, and Pb(II) ion concentration were investigated. Various kinetic models were also studied to assess adsorption kinetics of Pb(II) ions onto surface of MWC/ZIF nanocomposite. With reference to the obtained findings, the produced nanocomposite was assumed as an effective adsorption approach for removal of Pb(II) ions from effluent samples.
Fatemeh Sabermahani; Iman Aminaei
Abstract
The coconut peel waste (CPW) was chemically spiked with silica nanoparticles to develop a novel nanocomposite (SiO2/CPW). The new nanocomposite was characterized by FTIR, SEM and Dynamic Light Scattering method. Adsorption of Cd ions onto SiO2/CPW was studied in batch mode as a function of pH, contact ...
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The coconut peel waste (CPW) was chemically spiked with silica nanoparticles to develop a novel nanocomposite (SiO2/CPW). The new nanocomposite was characterized by FTIR, SEM and Dynamic Light Scattering method. Adsorption of Cd ions onto SiO2/CPW was studied in batch mode as a function of pH, contact time, adsorbent dosage and initial concentration and temperature. The maximum removal of Cd2+ions was at pH=6.5 and adsorbent dosage=0.1 g. The experiments showed that the adsorption process was quick and about 74.5% of total cadmium was removed within 5 min. Cadmium uptake by the new adsorbent was best described by pseudo-second order model. Using the equilibrium concentration constants obtained at different temperatures, various thermodynamic parameters have been calculated. The results indicated that Cadmium adsorption was feasible, spontaneous, and endothermic. The suggested sorbent proved the great potential in cadmium removal from water and wastewater.
Fatemeh Sabermahani; Fariba Honarmand
Abstract
In this study, Magnetic Fe3O4-walnut sawdust nanocompositewas synthesized and used for removal of lead from aqueous solution. The size, structural, optical and morphological properties of nanoparticles have been analyzed by Scanning Electron Microscope )SEM) and Dynamic Light Scattering method. The effect ...
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In this study, Magnetic Fe3O4-walnut sawdust nanocompositewas synthesized and used for removal of lead from aqueous solution. The size, structural, optical and morphological properties of nanoparticles have been analyzed by Scanning Electron Microscope )SEM) and Dynamic Light Scattering method. The effect of pH, contact time, adsorbent dose, initial concentration, ionic strength and the effect of temperature on the adsorption was checked out in a batch process mode. Using the equilibrium constants obtained at different temperatures, the thermodynamic results parameters were calculated as ∆G, ∆H and ∆S. The thermodynamic parameters showed that the uptake of lead is spontaneous and endothermic. The data were fitted with the Langmuir and Freundlich equations to describe the adsorption equilibrium. The maximum adsorption capacity by using Langmuir equation was calculated 12.99 mg/g. The kinetic data followed by Pseudo second. Owing to such outstanding features, Magnetic Fe3O4-walnut sawdust nanocompositeproved the great potential in adsorption lead removal from aqueous solutions.
Fatemeh Sabermahani; Leyli Irannejad; Nosrat Madadi Mahani
Volume 5, Issue 1 , March 2018, , Pages 33-38
Abstract
Polyaniline/maghemite magnetic nanocomposite (PANI/γ -Fe2O3 MNC) was used as active agents for removal of lead ions from aqueous media. Chemical co-precipitation method was used to prepare the maghemite nanoparticles. Subsequently, the MNC was synthesized through polymerization of aniline. ...
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Polyaniline/maghemite magnetic nanocomposite (PANI/γ -Fe2O3 MNC) was used as active agents for removal of lead ions from aqueous media. Chemical co-precipitation method was used to prepare the maghemite nanoparticles. Subsequently, the MNC was synthesized through polymerization of aniline. It was characterized by FT-IR.The efficiency of this MNC was estimated for Pb (II) removal by using batch method. The results showed that optimum conditions for lead removal were found to be at pH of 6, adsorbent dosage of 0.04 g and equilibrium contact time of 90 min. The kinetic of adsorption system have been studied based on the assumption of a pseudo-second order rate law. The adsorption isotherms were examined. The Freundlich adsorption isotherm model was found to represent the equilibrium adsorption isotherm better than Langmuir isotherm. The thermodynamic studies indicated that the adsorption was spontaneous and endothermic process for lead.
Reza Ansari; Naser Samadi; Bakhtiar Khodavirdilo
Volume 4, Issue 2 , September 2017, , Pages 50-60
Abstract
In this research poly (Styrene–Alternative-Maleic Anhydride) (SMA) and derivations of SMA with Melamine, (Melamine + 1,2 Diamino Ethane) and (Melamine + 1,3 Diamino Propane) CSMA-M, CSMA-ME and CSMA-MP were synthesized, respectively. This method is very simple, cheap, precise and used ...
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In this research poly (Styrene–Alternative-Maleic Anhydride) (SMA) and derivations of SMA with Melamine, (Melamine + 1,2 Diamino Ethane) and (Melamine + 1,3 Diamino Propane) CSMA-M, CSMA-ME and CSMA-MP were synthesized, respectively. This method is very simple, cheap, precise and used polymers recyclable to seven terms. The purpose of the present work was exploring the adsorption power of CSMA-M and its derived polymer to removed silver(I) ions from aqueous solution. In this research, batch adsorption tests were exhibited and the effect of different parameters on this removal process has been studied. The effects of pH, adsorption time, metal ion concentration and the acidic remedy on the adsorption process were optimized. The optimum pH for adsorption was found to be 6.0. In adsorption explores, remained Ag+ concentration arrives equilibrium in a short duration of 60 min. Maximum adsorption capacity, 67.57, 76.90 and 95.24 mg Ag+/g polymer CSMA-M, SMA–ME and SMA–MP respectively.showed that this adsorbents were appropriate for removing silver(I) from aqueous solution. The resins were characterized by Fourier transform Infra Red(FT-IR) spectroscopy, Scanning Electron Microscopy (SEM), X-ray diffraction(XRD) and Differential Scanning Calorimetry (DSC), (Thermo Gravimetric Analysis) TGA analysis.
